This video:
https://www.youtube.com/watch?v=Xilp56PVltI
will show you the steps to remove an Win32app from a Windows 10 desktop. It will utilise an existing Intune Application deployment policy to achieve this. It is able to do so because part of creating the initial deployment policy was the requirement to specify how to uninstall that same application. Thus, when you create an Application deployment policy in Intune you can use to add and remove that application from your environment.