if you haven’t seen my previous post (Skydrive Pro Primer) then I suggest you have a look so you know what I have discovered so far.
I fired up a new Windows 8 machine and installed Office 2013 Professional on it. When I selected the option to customize the installation I see:
As previously suspected, SkyDrive Pro is part of Office 2013.
Now if I look at my desktop I see a SkyDrive Pro 2013 icon.
Selecting the icon bring up the above window that asks which SharePoint Library I want to sync.
If I select the change button I can now select a new location on my local machine where the library will be sync’ed.